Title: Determination of the structural features of O-alkyl-S-2-(N,N-dialkylamino) ethyl alkylthiophosphonates from their electron ionization mass spectra Terentyev AG, Morozik YI, Rybal'chenko IV, Dudkin AV, Smirnov AO, Galyaev GV Ref: Journal of Analytical Chemistry, 71:1266, 2016 : PubMed
It is believed that information about the molecular structure of highly toxic O-alkyl-S-2(N,N-dialkylamino) ethyl alkylthiophosphonates (V-gases) obtained from their EI mass spectra is too insufficient. In particular, the determination of molecular weights and structures of radicals at phosphorus and oxygen atoms causes great difficulties. In this paper, solutions of these problems are proposed.
